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  • Design and Control of Highly Conductive Single-Molecule Junctions

    A Focus on the Metal–Molecule Interface

    Series series Chemistry and Material Science (R0)
    This thesis describes improvements to and control of the electrical conductance in single-molecule junctions (SMJs), which have potential applications in molecular electronics, with a focus on the bonding between the metal and molecule. In order to improve the electrical conductance, the π orbital of the molecule is directly bonded to the metal orbital, because anchoring groups, which were ... Read more

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    Series series Chemistry and Material Science (R0)
    The focus of this thesis is the computational modelling of transition metal bimetallic (nanoalloy) clusters. More specifically, the study of Pd-Pt, Ag-Pt, Au-Au and Pd-Au as a few tens of atoms in the gas phase. The author used a combination of global optimization techniques - coupled with a Gupta-type empirical many-body potential - and Density Functional Theory (DFT) calculations to study the ... Read more

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  • Nanocomposite-Based Electronic Tongue

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    Series series Chemistry and Material Science (R0)
    This book describes the fabrication of a frequency-based electronic tongue using a modified glassy carbon electrode (GCE), opening a new field of applying organic precursors to achieve nanostructure growth. It also presents a new approach to optimizing nanostructures by means of statistical analysis.The chemical vapor deposition (CVD) method was utilized to grow vertically aligned carbon nanotubes ... Read more

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  • Design, Synthesis and Characterization of new Supramolecular Architectures

    Series series Chemistry and Material Science (R0)
    This thesis focuses on the bottom-up design, construction and operation of supramolecular systems capable of behaving as devices and machines on the molecular scale, which is a topic of great interest in nanoscience and a fascinating challenge in nanotechnology. In particular, the systems investigated here include: polyviologen dendrimers capable of behaving as hosts and chargestoring devices; ... Read more

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  • Dynamic Chemical Processes on Solid Surfaces

    Chemical Reactions and Catalysis

    Series series Chemistry and Material Science (R0)
    In this book, the author determines that a surface is itself a new material for chemical reaction, and the reaction of the surface provides additional new materials on that surface. The revelation of that peculiarity is what makes this book different from an ordinary textbook, and this new point of view will help to provide a new impetus when graduate students and researchers consider their ... Read more

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  • Solar Energy for Fuels

    Series series Chemistry and Material Science (R0)
    The series Topics in Current Chemistry presents critical reviews of the present and future trends in modern chemical research. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science.The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive ... Read more

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  • Doping of Carbon Nanotubes

    Series series Chemistry and Material Science (R0)
    This book addresses the control of electronic properties of carbon nanotubes. It presents thermodynamic calculations of the formation of impurities and defects in the interaction of nanotubes with hydrogen, oxygen, nitrogen and boron, based on theoretical models of the formation of defects in carbon nanotubes. It is shown that doping and adsorption lead to changes in the electronic structure of ... Read more

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  • Portable Chemical Sensors

    Weapons Against Bioterrorism

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    Series series Springer Nature Proceedings excluding Computer Science
    Biosensors are making a large impact in environmental, food, biomedical, and other applications. In comparison to standard analytical detection methods, such as minimal sample preparation and handling, they offer advantages including real time detection, rapid detection of the analytes of concern, use of non-skilled personnel, and portability. The aim of this book is to focus on research related ... Read more

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  • New Smart Materials via Metal Mediated Macromolecular Engineering

    Series series Springer Nature Proceedings excluding Computer Science
    Control over macromolecular architecture and resulting material properties has been a central goal of polymer chemistry. There has been much interest in developing new synthetic routes to prepare smart materials with novel compositions and topologies for various applications. The considerable progress in the metal mediated macromolecular engineering over the past decade has had a major impact on ... Read more

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  • Photofunctionalization of Molecular Switch Based on Pyrimidine Ring Rotation in Copper Complexes

    Series series Chemistry and Material Science (R0)
    This book provides a detailed description of photofunctionalization of molecular switch based on pyrimidine ring rotational isomerization in copper complexes bearing two bidentate ligands. The most important features of this work focus on the properties associated with the rotational isomerization based on the two possible coordination geometries at the copper center derived from two nitrogen ... Read more

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  • Surface Modifications and Growth of Titanium Dioxide for Photo-Electrochemical Water Splitting

    Series series Engineering (R0)
    This outstanding thesis provides a wide-ranging overview of the growth of titanium dioxide thin films and its use in photo-electrochemicals such as water splitting. The context for water splitting is introduced with the theory of semiconductor-liquid junctions, which are dealt with in detail. In particular plasmonic enhancement of TiO2 by the addition of gold nanoparticles is considered in depth, ... Read more

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  • Conducting Polymer Hybrids

    Series series Chemistry and Material Science (R0)
    This book presents a comprehensive survey about conducting polymers and their hybrids with different materials. It highlights the topics pertinent to research and development in academia and in the industry. The book thus discusses the preparation and characterization of these materials, as well as materials properties and their processing. The current challenges in the field are addressed, and an ... Read more

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